CO2 Adsorption over Zinc Oxide Impregnated NaZSM-5 Synthesized Using Rice Husk Ash

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초록

Zinc oxide (5, 10 and 15 wt %) impregnated NaZSM-5 zeolite synthesized using rice husk ash as silica source was tested for CO2 adsorption. The materials were characterized by X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, CO2-temperature programmed desorption and Brunauer-Emmett-Teller techniques. The heat of the reaction (Delta H-r) derived from differential scanning calorbnetry analysis for NaZSM-5 (10%) to be 495 Btu/Lb. The maximum CO2 adsorption capacity of NaZSM-5 (10%) is 140 mg/g of sorbent. Extraction of silica from the agricultural waste, rice husk and its use in the zeolite synthesis is an added advantage in this study. Hence, from the study it is concluded that zinc oxide impregnated NaZSM-5 could be treated as novel material for CO2 adsorption as they were found to be regenerable, selective and recyclable.

키워드

NaZSM-5; Zinc oxide; Rice husk ash; CO2 adsorption; CARBON-DIOXIDE; ZEOLITE 13X; ALKALI; SILICA; N-2; SEPARATION; METHANE; BETA; EQUILIBRIA; SORBENTS
제목
CO2 Adsorption over Zinc Oxide Impregnated NaZSM-5 Synthesized Using Rice Husk Ash
저자
Hemalatha, Pushparaj; Palanichamy, Muthaihpillai; Murugesan, Velayutham; Kwon, Soon-Bark; Park, Duckshin; Cho, Youngmin; Jang, Hyun Tae
발행일
2011-06
유형
Article
저널명
Asian Journal of Chemistry
권
23
호
6
페이지
2806 ~ 2810